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IJSTR >> Volume 3- Issue 6, June 2014 Edition

International Journal of Scientific & Technology Research  
International Journal of Scientific & Technology Research

Website: http://www.ijstr.org

ISSN 2277-8616

Production Of Hydrogen By Anion Exchange Membrane Using AWE

[Full Text]



J. Donald Joe, D. B. Siva Kumar, P. Sivakumar



Keyword: AWE, Electrolysis, Hydrogen, Anion Exchange membrane, Alkaline, MEA, Deionised Water.



Abstract: This paper reports the performance of nickel oxide based electrode in alkaline anion exchange membrane water electrolysis. The membrane used is polystyrene based alkaline membrane and the electrode used is Nickel as cathode and Nickel oxide as anode. The electrochemical activity of the Nickel oxide is high compared to uncoated electrode. The AWE membrane electrode gave high current density at 300C with deionised water. The performance tends to increase by changing the temperature and alkaline solution. This results in increasing hydrogen production and be a promising technology in the future.



[1]. L. D.Silva, A. Bergel, D. Feron, and R. Basseguy, “Hydrogen production by electrolysis of a phosphate solution on a stainless steel Cathode”, International Journal of Hydrogen Energy, 35 (2010), pp:8561-8568.

[2]. K. Zeng, D. Zhang, “Recent progress in alkaline water electrolysis for Hydrogen production and applications”, Progress in Energy & Combustion Science, 36 (2010), 307-326.

[3]. G. Wei, Y. Wang, C. Huang, Q.G.Zhitao, and L. Xu,” The Stability of MEA in SPE water electrolysis for hydrogen production”, International Journal of Hydrogen Energy 35 (2010), pp:3951-3957.

[4]. M. Ni, M. K.H. Leung, K. Sumathy, and D.Y.C. Leung,” Potential of Renewable hydrogen production for energy supply in Hong Kong”, International Journal of Hydrogen Energy 31(2006), pp: 1401-1412.

[5]. A. Balabel, I.M. Sakr, and K. Ibrahim, “Potential of Renewable Hydrogen Production Technologies For energy requirements in Egypt”, Seventh Conference Of Egyptian Rural Development Water, energy and rural development, Faculty of Engineering, Menoufia University, 13-15 October 2009.

[6]. I. Schulte, D. Hart, and R. van der Vorst,” Issues affecting the acceptance of Hydrogen fuel”, International Journal of Hydrogen Energy 29(2004), pp: 677-685.

[7]. N. Lymberopoulos, "Hydrogen Production from Renewable", Centre for Renewable Energy Sources; 2005.

[8]. C. Koroneos, A. Dompros, G. Roumbas, and N. Moussiopoulos, ”Life cycle assessment of Hydrogen fuel production processes”, International Journal of Hydrogen Energy, 29(2004), pp: 1443-1450.

[9]. J. Nie, Y. Chen, R. F. Boehm, and S. Katukota, “A Photoelectrochemical Model of Proton Exchange Water Electrolysis for Hydrogen Production”, J. Heat Transfer 130, (2008).

[10]. W.G. Colella, M.Z. Jcobson, and D.M. Golden, “Switching to a U.S. hydrogen fuel cell Vehicle fleet: the resultant change in emissions, energy use, and greenhouse gases”, Journal of Power Sources, 150 (2005), pp: 150-181.

[11]. O. Ulleberge, "Modeling of advanced alkaline electrolyzers: a system approach"; J of Hydrogen energy, 28(2003), pp: 21-23, 2003.

[12]. S. Srinivasan, and F.J. Salzano, "Prospects for hydrogen production by water electrolysis to be competitive with conventional methods"; Int J Hydrogen Energy; 2(1977), pp: 53–59.

[13]. Carmo M, Fritz DL, Mergel J, Stolten D. A comprehensive review on PEM water electrolysis. Int J Hydrogen Energy2013;38:4901e34

[14]. Unlu M, Zhou J, Kohl PA. Anion exchange membrane fuel cells: experimental comparison of hydroxide and carbonate conductive ions. Electrochem Solid State Lett 2009;12(3):B27e30.

[15]. Yu EH, Scott K. Development of direct methanol alkaline fuel cells using anion exchange membranes. J Power Sources 2004;137:248e56.

[16]. Gu S, Cai R, Chen Z, Sun M, Liu Y, He G, et al. A soluble and highly conductive ionomer for high performance hydroxide exchange membrane fuel cells. Angew Chem Int Ed 2009;48:1e5.

[17]. Merle G, Wessling M, Nijimeijer K. Anion exchange membranes for alkaline fuel cells: a review. J Memb Sci 2011;377:1e35.

[18]. Xiao L, Zhang S, Pan J, Yang C, He M, Zhuang L, et al. First implementation of alkaline polymer electrolyte water electrolysis working only with pure water. Energy Environ Sci 2012;5:7869e71.

[19]. Tanaka M, Koike M, Miyatake K, Watanabe M. Synthesis and properties of anion conductive ionomers containing fluorenyl groups for alkaline fuel cell applications. Polym Chem 2011;2:99e106.

[20]. Miles MH, Kissel G, Lu PWT, Srinivasan S. Effect of temperature on electrode kinetic parameters for hydrogen and oxygen evolution reactions on nickel electrodes in alkaline solutions. J Electrochem Soc 1976;123:332e6.

[21]. Ferreira AC, Gonzalez ER, Ticianelli EA, Avaca AA, Matvienko B. The effect of temperature on the water electrolysis reactions on nickel and nickel based codeposits. J Appl Electrochem 1988;18:894e8.

[22]. Pletcher D, Li X, Wang S. A comparison of cathodes for zero gap alkaline water electrolysers for hydrogen production. Int J Hydrogen Energy 2012;37:7429e35.

[23]. Li X, Walsha FC, Pletcher D. Nickel based electrocatalysts for oxygen evolution in high current density, alkaline water electrolysers. Phys Chem Chem Phys 2011;13:1162e7.

[24]. Bronoel G, Reby J. Mechanism of oxygen evolution in basic medium at a Ni electrode. Electrochim Acta 1980;25:973e6.

[25]. Cai GF, Tu JP, Zhang J, Mai YJ, Lu Y, Gu CD, et al. An efficient route to a porous NiO/reduced graphene oxide hybrid film with highly improved electrochromic properties. Nanoscale 2012;4:5724e30.

[26]. Zeng K, Zhang D. Recent progress in alkaline water electrolysis for hydrogen production and applications. Prog Energy Combust Sci 2010;36:307e26.