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Investigations On The Optical And Mechanical Properties Of Non Linear Optical Creatininium Phosphite Single Crystal
[Full Text]
AUTHOR(S)
Sindhusha S, Padma C M, Amalanathan M
KEYWORDS
Monoclinic, band gap, nonlinear susceptibility, polarizability, mechanical property
ABSTRACT
The main objective of this study is to grow and characterize optically transparent single crystals of Creatininium phosphite by slow evaporation technique at room temperature. Single crystal X-ray diffraction analysis confirms the lattice parameters and the centro symmetrical nature of the synthesized crystal. The optical constants such as band gap energy and refractive index of the grown crystal were evaluated by UV-visible transmittance spectral study. The HOMO, LUMO energy and the energy gap were calculated and analysed. Photoluminescence spectral study confirms the emission behaviour of the gown crystal. The theoretical non linear optical parameter such as dipole moment, polarizability, hyper polarizability and second order hyper polarizability were calculated and analyzed. Third order optical nonlinearity was confirmed by Z-scan technique. Second Harmonic Generation was confirmed by Kurtz Perry powder technique. Mechanical property of the grown crystal was analysed by using vickers microhardness analysis.
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